Both the parallelism between chemical and electrochemical transfers and the role played by the electrostatic image in the latter case are discussed. Marcus ra 1964 chemical and electrochemical electrontransfer theory. Kinetic studies of simple electron transfer systems in solution and at electrodes have revealed a number of interesting and simplifying features. Abstract electron transfer across the moleculesemiconductor interface is a fundamental process that is relevant to many applications of nanoparticles, such as dyesensitized solar cells and molecular electronics. Request pdf chemical and electrochemical electrontransfer theory one of the active areas in reaction kinetics during the postwar years has been that of. Chemical and electrochemical electrontransfer theory annual. A classification of reactants is employed throughout, based in part on differences in the theoretical treatment. These reactions constitute one type of oxidationreduction process and include both chemical and electro chemical systems. Chemical and electrochemical electrontransfer theory request. The reorganization energy, which is a measure of the freeenergy change associated with solute and solvent rearrangements, is a key quantity for calculating rate constants for these reactions. Chemical and electrochemical electrontransfer theory. Electron transfer et is one of the most ubiquitous and fundamental phenomena in chemistry, physics, and. Observations and theories of quantum effects in proton transfer. One of the active areas in reaction kinetics during the postwar years has been that of electrontransfer reactions.
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